The pair have teamed up for a cover of Howlin Wolf's 'Evil', with Jones performing the vocals and White producing the track.
The song will be released through White's Third Man Records label as part of a 'Blue Series' project on March 19.
The 'Blue Series' will also include a new version of Jones's 2002 track 'Jezebel'.
Meanwhile, White recently released his new single 'Love Interruption', while his upcoming album Blunderpuss will be available on April 24.
> Jack White reveals new solo track 'Machine Gun Silhouette' - listen
Listen to Tom Jones and Jack White's 'Evil' below: